Comprehensive results on the production of unidentified charged particles, $\pi^{\pm}$, $\rm{K}^{\pm}$, $\rm{K}^{0}_{S}$, $\rm{K}$*(892)$^{0}$, $\rm{p}$, $\overline{\rm{p}}$, $\phi$(1020), $\Lambda$, $\overline{\Lambda}$, $\Xi^{-}$, $\overline{\Xi}^{+}$, $\Omega^{-}$ and $\overline{\Omega}^{+}$ hadrons in proton-proton (pp) collisions at $\sqrt{s}$ = 7 TeV at midrapidity ($|y| < 0.5$) as a function of charged-particle multiplicity density are presented. In order to avoid auto-correlation biases, the actual transverse momentum ($p_{\rm{T}}$) spectra of the particles under study and the event activity are measured in different rapidity windows. In the highest multiplicity class, the charged-particle density reaches about 3.5 times the value measured in inelastic collisions. While the yield of protons normalized to pions remains approximately constant as a function of multiplicity, the corresponding ratios of strange hadrons to pions show a significant enhancement that increases with increasing strangeness content. Furthermore, all identified particle to pion ratios are shown to depend solely on charged-particle multiplicity density, regardless of system type and collision energy. The evolution of the spectral shapes with multiplicity and hadron mass shows patterns that are similar to those observed in p-Pb and Pb-Pb collisions at LHC energies. The obtained $p_{\rm{T}}$ distributions and yields are compared to expectations from QCD-based pp event generators as well as to predictions from thermal and hydrodynamic models. These comparisons indicate that traces of a collective, equilibrated system are already present in high-multiplicity pp collisions.
The pseudorapidity ($\eta$) and transverse-momentum ($p_{\rm T}$) distributions of charged particles produced in proton-proton collisions are measured at the centre-of-mass energy $\sqrt{s}$ = 13 TeV. The pseudorapidity distribution in $|\eta|<$ 1.8 is reported for inelastic events and for events with at least one charged particle in $|\eta|<$ 1. The pseudorapidity density of charged particles produced in the pseudorapidity region $|\eta|<$ 0.5 is 5.31 $\pm$ 0.18 and 6.46 $\pm$ 0.19 for the two event classes, respectively. The transverse-momentum distribution of charged particles is measured in the range 0.15 $<$ $p_{\rm T}$ $<$ 20 GeV/c and $|\eta|<$ 0.8 for events with at least one charged particle in $|\eta|<$ 1. The correlation between transverse momentum and particle multiplicity is also investigated by studying the evolution of the spectra with event multiplicity. The results are compared with calculations from PYTHIA and EPOS Monte Carlo generators.
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