This publication describes the methods used to measure the centrality of inelastic Pb-Pb collisions at a center-of-mass energy of 2.76 TeV per colliding nucleon pair with ALICE. The centrality is a key parameter in the study of the properties of QCD matter at extreme temperature and energy density, because it is directly related to the initial overlap region of the colliding nuclei. Geometrical properties of the collision, such as the number of participating nucleons and number of binary nucleon-nucleon collisions, are deduced from a Glauber model with a sharp impact parameter selection, and shown to be consistent with those extracted from the data. The centrality determination provides a tool to compare ALICE measurements with those of other experiments and with theoretical calculations.

A detailed study of pseudorapidity densities and multiplicity distributions of primary charged particles produced in proton-proton collisions, at $\sqrt{s} =$ 0.9, 2.36, 2.76, 7 and 8 TeV, in the pseudorapidity range $|\eta|<2$, was carried out using the ALICE detector. Measurements were obtained for three event classes: inelastic, non-single diffractive and events with at least one charged particle in the pseudorapidity interval $|\eta|<1$. The use of an improved track-counting algorithm combined with ALICE's measurements of diffractive processes allows a higher precision compared to our previous publications. A KNO scaling study was performed in the pseudorapidity intervals $|\eta|<$ 0.5, 1.0 and 1.5. The data are compared to other experimental results and to models as implemented in Monte Carlo event generators PHOJET and recent tunes of PYTHIA6, PYTHIA8 and EPOS.

The pseudorapidity density and multiplicity distribution of charged particles produced in proton-proton collisions at the LHC, at a centre-of-mass energy $\sqrt{s} = 7$ TeV, were measured in the central pseudorapidity region |$\eta$| < 1. Comparisons are made with previous measurements at $\sqrt{s}$ = 0.9 TeV and 2.36 TeV. At $\sqrt{s}$ = 7 TeV, for events with at least one charged particle in |$\eta$| < 1, we obtain dNch/deta = 6.01 $\pm$ 0.01 (stat.) $^{+0.20}_{-0.12}$ (syst.). This corresponds to an increase of 57.6% $\pm$ 0.4% (stat.) $^{+3.6}_{-1.8}$% (syst.) relative to collisions at 0.9 TeV, significantly higher than calculations from commonly used models. The multiplicity distribution at 7 TeV is described fairly well by the negative binomial distribution.

Charged-particle production was studied in proton-proton collisions collected at the LHC with the ALICE detector at centre-of-mass energies 0.9 TeV and 2.36 TeV in the pseudorapidity range |$\eta$| < 1.4. In the central region (|$\eta$| < 0.5), at 0.9 TeV, we measure charged-particle pseudorapidity density dNch/deta = 3.02 $\pm$ 0.01 (stat.) $^{+0.08}_{-0.05}$ (syst.) for inelastic interactions, and dNch/deta = 3.58 $\pm$ 0.01 (stat.) $^{+0.12}_{-0.12}$ (syst.) for non-single-diffractive interactions. At 2.36 TeV, we find dNch/deta = 3.77 $\pm$ 0.01 (stat.) $^{+0.25}_{-0.12}$ (syst.) for inelastic, and dNch/deta = 4.43 $\pm$ 0.01 (stat.) $^{+0.17}_{-0.12}$ (syst.) for non-single-diffractive collisions. The relative increase in charged-particle multiplicity from the lower to higher energy is 24.7% $\pm$ 0.5% (stat.) $^{+5.7}_{-2.8}$% (syst.) for inelastic and 23.7% $\pm$ 0.5% (stat.) $^{+4.6}_{-1.1}$% (syst.) for non-single-diffractive interactions. This increase is consistent with that reported by the CMS collaboration for non-single-diffractive events and larger than that found by a number of commonly used models. The multiplicity distribution was measured in different pseudorapidity intervals and studied in terms of KNO variables at both energies. The results are compared to proton-antiproton data and to model predictions.

A measurement of the underlying event (UE) activity in proton-proton collisions is performed using events with charged-particle jets produced in the central pseudorapidity region (abs(eta[jet]) < 2) and with transverse momentum 1<= pt[jet] < 100 GeV. The analysis uses a data sample collected at a centre-of-mass energy of 2.76 TeV with the CMS experiment at the LHC. The UE activity is measured as a function of pt[jet] in terms of the average multiplicity and scalar sum of transverse momenta (pt) of charged particles, with abs(eta) < 2 and pt > 0.5 GeV, in the azimuthal region transverse to the highest pt jet direction. By further dividing the transverse region into two regions of smaller and larger activity, various components of the UE activity are separated. The measurements are compared to previous results at 0.9 and 7 TeV, and to predictions of several Monte Carlo event generators, providing constraints on the modelling of the UE dynamics.

Multiplicity ($N_{\rm ch}$) distributions and transverse momentum ($p_{\rm T}$) spectra of inclusive primary charged particles in the kinematic range of $|\eta| < 0.8$ and 0.15 GeV/$c$$< p_{T} <$ 10 GeV/$c$ are reported for pp, p-Pb, Xe-Xe and Pb-Pb collisions at centre-of-mass energies per nucleon pair ranging from $\sqrt{s_{\rm NN}} = 2.76$ TeV up to $13$ TeV. A sequential two-dimensional unfolding procedure is used to extract the correlation between the transverse momentum of primary charged particles and the charged-particle multiplicity of the corresponding collision. This correlation sharply characterises important features of the final state of a collision and, therefore, can be used as a stringent test of theoretical models. The multiplicity distributions as well as the mean and standard deviation derived from the $p_{\rm T}$ spectra are compared to state-of-the-art model predictions. Providing these fundamental observables of bulk particle production consistently across a wide range of collision energies and system sizes can serve as an important input for tuning Monte Carlo event generators.

This note describes the details of the analysis of charged-particle pseudorapidity densities and multiplicity distributions measured by the ALICE detector in pp collisions at $\sqrt{s}$ = 0.9 and 7 TeV in specific phase space regions. The primary goal of the analysis is to provide reference measurements for Monte Carlo tuning. The pseudorapidity range |h| < 0.8 is considered and a lower $p_T$ cut is applied, at 0.15, 0.5 GeV/c and at 1 GeV/c. The choice of such phase space regions to measure the charged-particle multiplicity allows a direct comparison with the analogous results obtained by other LHC collaborations, namely ATLAS and CMS. The class of events considered are those having at least one charged particle in the kinematical ranges just described. In the note, the analysis procedure is presented, together with the corrections applied to the data, and the systematic uncertainty evaluation. The comparison of the results with different Monte Carlo generators is also shown.