Differential cross sections of charged particles in inelastic pp collisions as a function of $p_{\rm T}$ have been measured at $\sqrt{s}=$ 0.9, 2.76 and 7 TeV at the LHC. The $p_{\rm T}$ spectra are compared to NLO-pQCD calculations. Though the differential cross section for an individual $\sqrt{s}$ cannot be described by NLO-pQCD, the relative increase of cross section with $\sqrt{s}$ is in agreement with NLO-pQCD. Based on these measurements and observations, procedures are discussed to construct pp reference spectra at $\sqrt{s} =$ 2.76 and 5.02 TeV up to $p_{\rm T}$ = 50 GeV/$c$ as required for the calculation of the nuclear modification factor in nucleus-nucleus and proton-nucleus collisions.

The multiplicity and pseudorapidity distributions of inclusive photons have been measured at forward rapidities ($2.3 < \eta < 3.9$) in proton-proton collisions at three center-of-mass energies, $\sqrt{s}=0.9$, 2.76 and 7 TeV using the ALICE detector. It is observed that the increase in the average photon multiplicity as a function of beam energy is compatible with both a logarithmic and a power-law dependence. The relative increase in average photon multiplicity produced in inelastic pp collisions at 2.76 and 7 TeV center-of-mass energies with respect to 0.9 TeV are 37.2% $\pm$ 0.3% (stat) $\pm$ 8.8% (sys) and 61.2% $\pm$ 0.3% (stat) $\pm$ 7.6% (sys), respectively. The photon multiplicity distributions for all center-of-mass energies are well described by negative binomial distributions. The multiplicity distributions are also presented in terms of KNO variables. The results are compared to model predictions, which are found in general to underestimate the data at large photon multiplicities, in particular at the highest center-of-mass energy. Limiting fragmentation behavior of photons has been explored with the data, but is not observed in the measured pseudorapidity range.

We present measurements of Underlying Event observables in pp collisions at $\sqrt{s}$ = 0.9 and 7 TeV. The analysis is performed as a function of the highest charged-particle transverse momentum $p_{\rm T, LT}$ in the event. Different regions are defined with respect to the azimuthal direction of the leading (highest transverse momentum) track: Toward, Transverse and Away. The Toward and Away regions collect the fragmentation products of the hardest partonic interaction. The Transverse region is expected to be most sensitive to the Underlying Event activity. The study is performed with charged particles above three different $p_{\rm T}$ thresholds: 0.15, 0.5 and 1.0 GeV/$c$. In the Transverse region we observe an increase in the multiplicity of a factor 2-3 between the lower and higher collision energies, depending on the track $p){\rm T}$ threshold considered. Data are compared to Pythia 6.4, Pythia 8.1 and Phojet. On average, all models considered underestimate the multiplicity and summed $p_{\rm T}$ in the Transverse region by about 10-30%.

We present the first wide-range measurement of the charged-particle pseudorapidity density distribution, for different centralities (the 0-5%, 5-10%, 10-20%, and 20-30% most central events) in Pb-Pb collisions at $\sqrt{s_{\rm NN}} = 2.76$ TeV at the LHC. The measurement is performed using the full coverage of the ALICE detectors, $-5.0 < \eta < 5.5$, and employing a special analysis technique based on collisions arising from LHC "satellite" bunches. We present the pseudorapidity density as a function of the number of participating nucleons as well as an extrapolation to the total number of produced charged particles ($N_{\rm ch} = 17165 \pm 772$ for the 0-5% most central collisions). From the measured ${\rm d}N_{\rm ch}/{\rm d}\eta$ distribution we derive the rapidity density distribution, ${\rm d}N_{\rm ch}/{\rm d}y$, under simple assumptions. The rapidity density distribution is found to be significantly wider than the predictions of the Landau model. We assess the validity of longitudinal scaling by comparing to lower energy results from RHIC. Finally the mechanisms of the underlying particle production are discussed based on a comparison with various theoretical models.

The first measurement of two-pion Bose-Einstein correlations in central Pb-Pb collisions at $\sqrt{s_{\rm NN}} = 2.76$ TeV at the Large Hadron Collider is presented. We observe a growing trend with energy now not only for the longitudinal and the outward but also for the sideward pion source radius. The pion homogeneity volume and the decoupling time are significantly larger than those measured at RHIC.

The pseudorapidity density and multiplicity distribution of charged particles produced in proton-proton collisions at the LHC, at a centre-of-mass energy $\sqrt{s} = 7$ TeV, were measured in the central pseudorapidity region |$\eta$| < 1. Comparisons are made with previous measurements at $\sqrt{s}$ = 0.9 TeV and 2.36 TeV. At $\sqrt{s}$ = 7 TeV, for events with at least one charged particle in |$\eta$| < 1, we obtain dNch/deta = 6.01 $\pm$ 0.01 (stat.) $^{+0.20}_{-0.12}$ (syst.). This corresponds to an increase of 57.6% $\pm$ 0.4% (stat.) $^{+3.6}_{-1.8}$% (syst.) relative to collisions at 0.9 TeV, significantly higher than calculations from commonly used models. The multiplicity distribution at 7 TeV is described fairly well by the negative binomial distribution.

Charged-particle production was studied in proton-proton collisions collected at the LHC with the ALICE detector at centre-of-mass energies 0.9 TeV and 2.36 TeV in the pseudorapidity range |$\eta$| < 1.4. In the central region (|$\eta$| < 0.5), at 0.9 TeV, we measure charged-particle pseudorapidity density dNch/deta = 3.02 $\pm$ 0.01 (stat.) $^{+0.08}_{-0.05}$ (syst.) for inelastic interactions, and dNch/deta = 3.58 $\pm$ 0.01 (stat.) $^{+0.12}_{-0.12}$ (syst.) for non-single-diffractive interactions. At 2.36 TeV, we find dNch/deta = 3.77 $\pm$ 0.01 (stat.) $^{+0.25}_{-0.12}$ (syst.) for inelastic, and dNch/deta = 4.43 $\pm$ 0.01 (stat.) $^{+0.17}_{-0.12}$ (syst.) for non-single-diffractive collisions. The relative increase in charged-particle multiplicity from the lower to higher energy is 24.7% $\pm$ 0.5% (stat.) $^{+5.7}_{-2.8}$% (syst.) for inelastic and 23.7% $\pm$ 0.5% (stat.) $^{+4.6}_{-1.1}$% (syst.) for non-single-diffractive interactions. This increase is consistent with that reported by the CMS collaboration for non-single-diffractive events and larger than that found by a number of commonly used models. The multiplicity distribution was measured in different pseudorapidity intervals and studied in terms of KNO variables at both energies. The results are compared to proton-antiproton data and to model predictions.

The ratio of the yields of antiprotons to protons in pp collisions has been measured by the ALICE experiment at $\sqrt{s} = 0.9$ and $7$ TeV during the initial running periods of the Large Hadron Collider(LHC). The measurement covers the transverse momentum interval $0.45 < p_{\rm{t}} < 1.05$ GeV/$c$ and rapidity $|y| < 0.5$. The ratio is measured to be $R_{|y| < 0.5} = 0.957 \pm 0.006 (stat.) \pm 0.014 (syst.)$ at $0.9$ TeV and $R_{|y| < 0.5} = 0.991 \pm 0.005 (stat.) \pm 0.014 (syst.)$ at $7$ TeV and it is independent of both rapidity and transverse momentum. The results are consistent with the conventional model of baryon-number transport and set stringent limits on any additional contributions to baryon-number transfer over very large rapidity intervals in pp collisions.

Bose-Einstein correlations between identical particles are measured in samples of proton-proton collisions at 0.9 and 7 TeV centre-of-mass energies, recorded by the CMS experiment at the LHC. The signal is observed in the form of an enhancement of number of pairs of same-sign charged particles with small relative momentum. The dependence of this enhancement on kinematic and topological features of the event is studied.

Measurements of inclusive charged-hadron transverse-momentum and pseudorapidity distributions are presented for proton-proton collisions at sqrt(s) = 0.9 and 2.36 TeV. The data were collected with the CMS detector during the LHC commissioning in December 2009. For non-single-diffractive interactions, the average charged-hadron transverse momentum is measured to be 0.46 +/- 0.01 (stat.) +/- 0.01 (syst.) GeV/c at 0.9 TeV and 0.50 +/- 0.01 (stat.) +/- 0.01 (syst.) GeV/c at 2.36 TeV, for pseudorapidities between -2.4 and +2.4. At these energies, the measured pseudorapidity densities in the central region, dN(charged)/d(eta) for |eta| < 0.5, are 3.48 +/- 0.02 (stat.) +/- 0.13 (syst.) and 4.47 +/- 0.04 (stat.) +/- 0.16 (syst.), respectively. The results at 0.9 TeV are in agreement with previous measurements and confirm the expectation of near equal hadron production in p-pbar and pp collisions. The results at 2.36 TeV represent the highest-energy measurements at a particle collider to date.